The enthalpy change for the reaction,$H_{2(g)} + C_2H_{4(g)} \to C_2H_{6(g)}$ is $......$ $kcal \ mol^{-1}$. The bond energies are,$[e_{H-H} = 103, e_{C-H} = 99, e_{C-C} = 80]$ and $[e_{C=C} = 145] \ kcal \ mol^{-1}$.

From the following data:
$CH_3OH_{(l)} + \frac{3}{2}O_{2(g)} \longrightarrow CO_{2(g)} + 2H_2O_{(l)}$; $\Delta_rH^{\circ} = -726 \ kJ \ mol^{-1}$
$H_{2(g)} + \frac{1}{2}O_{2(g)} \longrightarrow H_2O_{(l)}$; $\Delta_rH^{\circ} = -286 \ kJ \ mol^{-1}$
$C_{(graphite)} + O_{2(g)} \longrightarrow CO_{2(g)}$; $\Delta_rH^{\circ} = -393 \ kJ \ mol^{-1}$
The standard enthalpy of formation of $CH_3OH_{(l)}$ in $kJ \ mol^{-1}$ is:

The lowest value of heat of neutralization is obtained for

Consider the following reactions:
$(i)$ $H_{(aq)}^{+} + OH^{-}_{(aq)} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_1 \ kJ \ mol^{-1}$
$(ii)$ $H_{2_{(g)}} + \frac{1}{2} O_{2_{(g)}} \longrightarrow H_2O_{(l)}$,$\Delta H = -X_2 \ kJ \ mol^{-1}$
$(iii)$ $CO_{2_{(g)}} + H_{2_{(g)}} \longrightarrow CO_{(g)} + H_2O_{(l)}$,$\Delta H = -X_3 \ kJ \ mol^{-1}$
$(iv)$ $C_2H_{2_{(g)}} + \frac{5}{2} O_{2_{(g)}} \longrightarrow 2CO_{2_{(g)}} + H_2O_{(l)}$,$\Delta H = -X_4 \ kJ \ mol^{-1}$
Enthalpy of formation of $H_2O_{(l)}$ is

The atomisation enthalpy of $CH_4$ is $1660 \ kJ \ mol^{-1}$. The $C-H$ bond enthalpy of each successive step in $CH_4$ $\rightarrow CH_3$ $\rightarrow CH_2$ $\rightarrow CH$ are $+15, +30$ and $+45 \ kJ \ mol^{-1}$ higher than the mean bond enthalpy of $C-H$ bonds,respectively. The bond enthalpy of the last $C-H$ unit is

$AB$,$A_2$,and $B_2$ are diatomic molecules. Enthalpies of dissociation of $AB$,$A_2$,and $B_2$ are in the ratio of $1:1:0.5$. Enthalpy of formation of $AB$,$\Delta_f H = -100 \ kJ \ mol^{-1}$. Find the dissociation enthalpy of $A_2$?
Reaction : $\frac{1}{2} A_2 + \frac{1}{2} B_2 \to AB$